Synthesis and Structure of Cyclometallated Palladium Binuclear Complexes with Bridging Carboxylate Ligands

Yu. E. Makarevich; Макаревич Ю. Е.; M. N. Vargaftik; Варгафтик М. Н.; M. Yu. Nesterenko; Нестеренко М. Ю.; M. V. Panina; Панина М. В.; A. S. Popova; Попова А. С.; I. V. Skabitsky; Скабицкий И. В.; O. V. Sulimova; Сулимова О. В.; E. A. Sosunov; Сосунов Е. А.; N. K. Ogarkova; Огаркова Н. К.; I. A. Yakushev; Якушев И. А.

doi:10.31857/S0044457X2360127X

Synthesis and Structure of Cyclometallated Palladium Binuclear Complexes with Bridging Carboxylate Ligands

Authors: Makarevich Y.E.¹, Vargaftik M.N.¹, Nesterenko M.Y.¹, Panina M.V.¹, Popova A.S.¹, Skabitsky I.V.¹, Sulimova O.V.¹, Sosunov E.A.¹, Ogarkova N.K.¹, Yakushev I.A.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 9 (2023)
Pages: 1244-1254
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136489
DOI: https://doi.org/10.31857/S0044457X2360127X
EDN: https://elibrary.ru/WKRLKU
ID: 136489

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Abstract

New bimetallic pivalate Pd(II) complex [PdNi(OOCtBu)4(HOOCtBu)] (I) has been synthesized from [PdNi(OOCMe)4] and used as a starting reagent in a further complexation reaction. Cyclometallated binuclear carboxylate palladium complexes [(OOCMe)Pd(2‑phpy)]2 (II) and [(OOCtBu)Pd(2‑phpy)]2 (III) have been obtained by the reaction between heterometallic compounds [Pd(OOCR)4Ni] (R = Me, tBu) and 2-phenylpyridine (2-phpy). The reaction proceeds at room temperature under mild conditions. All the compounds obtained have been isolated in crystalline form from a medium of nonpolar solvents, characterized by single-crystal X-ray diffraction analysis, and deposited at the Cambridge Crystallographic Data Center (CCDC nos. 2256606 for I, 2247942 for II, and 2247943 for III).

Keywords

heterometallic complexes, palladium, cyclometalation, carboxylates, binuclear compounds, synthesis, 2-phenylpyridine, X-ray diffraction

References

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