Ba2Gd2 – xSmxGe4O13: Luminescence Properties, Prospects for Non-Contact Temperature Sensing Applications and Light-Emitting Diodes

A. V. Chvanova; Чванова А. В.; O. A. Lipina; Липина О. А.; A. Yu. Chufarov; Чуфаров А. Ю.; A. P. Tyutyunnik; Тютюнник А. П.; Ya. V. Baklanova; Бакланова Я. В.; L. L. Surat; Сурат Л. Л.; V. G. Zubkov; Зубков В. Г.

doi:10.31857/S0044457X22601353

Ba2Gd2 – xSmxGe4O13: Luminescence Properties, Prospects for Non-Contact Temperature Sensing Applications and Light-Emitting Diodes

Authors: Chvanova A.V.¹, Lipina O.A.¹, Chufarov A.Y.¹, Tyutyunnik A.P.¹, Baklanova Y.V.¹, Surat L.L.¹, Zubkov V.G.¹
Affiliations:
1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences
Issue: Vol 68, No 3 (2023)
Pages: 383-392
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://journals.rcsi.science/0044-457X/article/view/136343
DOI: https://doi.org/10.31857/S0044457X22601353
EDN: https://elibrary.ru/JCHJRU
ID: 136343

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Abstract
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Abstract

Tetragermanates Ba2Gd2 – xSmxGe4O13 (x = 0.025–0.8) have been synthesized by the solid-phase method. Solid solutions crystallize in the monoclinic crystal system (space group С2/с, Z = 4) and are members of a small family of inorganic compounds containing [Ge4O13]10– anions. The photoluminescence properties of germanates upon excitation by radiation with λex = 275 nm have been studied. The spectra of the compounds show a broad band with a maximum at 313 nm and a set of lines in the range of 525–730 nm, corresponding to intraconfigurational 4f–4f transitions in Gd3+ and Sm3+ ions. It has been found that germanate Ba2Gd1.95Sm0.05Ge4O13 has the maximum luminescence intensity. For this sample, the color characteristics and the temperature dependences of the intensity ratios of the main luminescence bands upon heating to 498 K have been studied. It has been concluded that Ba2Gd1.95Sm0.05Ge4O13 can be used as a material for non-contact temperature sensing and light emitting diodes.

Keywords

luminescence, germanate, samarium

References

Brites C.D.S., Millán A., Carlos L.D. // Handb. Phys. Chem. Rare Earths. 2016. V. 49. P. 339. https://doi.org/10.1016/bs.hpcre.2016.03.005
Brites C.D.S., Lima P.P., Silva et al. // Nanoscale. 2012. V. 4. P. 4799. https://doi.org/10.1039/C2NR30663H
Rai V.K., Rai S.B. // Appl. Phys. B. 2007. V. 87. P. 323. https://doi.org/10.1007/s00340-007-2592-z
Dramićanin M. Chapter 6 – Lanthanide and Transition Metal Ion Doped Materials for Luminescence Temperature Sensing in Luminescence Thermometry: Methods, Materials, and Applications, Woodhead Publishing Series in Electronic and Optical Materials. 2018. P. 113–157.
Zhu K., Zhou H., Qiu J. et al. // J. Alloys Compd. 2021. V. 890. P. 161844. https://doi.org/10.1016/j.jallcom.2021.161844
Nikolić M.G., Jovanović D.J., Đorđević V. et al. // Phys. Scr. 2012. P. 014063. https://doi.org/10.1088/0031-8949/2012/T149/014063
Suta M., Mejerink A. // Adv. Theory Simul. 2020. V. 3. P. 2000176. https://doi.org/10.1002/adts.202000176
Li J., Yan J., Wen D. et al. // J. Mater. Chem. C. 2016. V. 4. P. 8611. https://doi.org/10.1039/C6TC02695H
Ma Y., Tang S., Ji C. et al. // J. Lumin. 2022. V. 242. P. 118530. https://doi.org/10.1016/j.jlumin.2021.118530
Ji C., Huang Z., Tian X. et al. // J. Alloys Compd. 2020. V. 825. P. 154176. https://doi.org/10.1016/j.jallcom.2020.154176
Ji C., Huang Z., Tian X. et al. // J. Lumin. 2021. V. 232. P. 117775. https://doi.org/10.1016/j.jlumin.2020.117775
Singh V., Lakshminarayana G., Singh N. // Optik. 2020. V. 211. P. 164272. https://doi.org/10.1016/j.ijleo.2020.164272
Liu H., Guo S., Hao Y. et al. // J. Lumin. 2012. V. 132. № 11. P. 2908. https://doi.org/10.1016/j.jlumin.2012.06.006
Mei L., Liu H., Liao L. et al. // Scientif. Rep. 2017. V. 7. P. 15171. https://doi.org/10.1038/s41598-017-15595-z
Helode S.J., Kadam A.R., Dhoble S.J. // Chem. Data Collect. 2020. V. 40. P. 100881. https://doi.org/10.1016/j.cdc.2022.100881
Денисова Л.Т., Молокеев М.С., Каргин Ю.Ф. и др. // Журн. неорган. химии. 2021. Т. 66. № 12. С. 1700. https://doi.org/10.1134/S0036023621120020
Горбунов Ю.А., Максимов Б.А., Белов Н.В. // Докл. АН СССР. 1973. Т. 211. С. 591.
Masuda T., Chakoumakos B.C., Nygren C.L. et al. // J. Solid State Chem. 2003. V. 176. P. 175. https://doi.org/10.1016/S0022-4596(03)00387-6
Redhammer G.J., Roth G. // J. Solid State Chem. 2004. V. 177. P. 2714. https://doi.org/10.1016/j.jssc.2004.04.016
Sanjeewa L.D., McGuire M.A., McMillen C.D. et al. // Chem. Mater. 2017. V. 29. P. 1404. https://doi.org/10.1021/acs.chemmater.6b05320
Ananias D., Paz F.A.A., Carlos L.D. et al. // Eur. J. Inorg. Chem. 2018. V. 2018. № 20. P. 2444. https://doi.org/10.1002/ejic.201800153
Tyutyunnik A.P., Chufarov A.Yu., Surat L.L. et al. // Mendeleev Commun. 2018. V. 28. P. 661. https://doi.org/10.1016/j.mencom.2018.11.035
Lipina O.A., Surat L.L., Chufarov A.Y. et al. // Dalton Trans. 2021. V. 50. P. 10935. https://doi.org/10.1039/d1dt01780b
Toby B.H. // J. Appl. Crystallogr. B. 2001. V. 34. P. 210. https://doi.org/10.1107/S0021889801002242
Larson A.C., Von Dreele R.B. General Structure Analysis System (GSAS), Los Alamos National Laboratory Report LAUR 86-748, Los Alamos, NM, 2004.
Shannon R.D. // Acta Crystallogr., Sect. A. 1976. V. 32. P. 751. https://doi.org/10.1107/S0567739476001551
Ullah I., Shah S.K., Rooh G. et al. // Opt. Mater. 2021. V. 111. P. 110657. https://doi.org/10.1016/j.optmat.2020.110657
Baklanova Y.V., Maksimova L.G., Lipina O.A. et al. // J. Lumin. 2020. V. 224. P. 117315. https://doi.org/10.1016/j.jlumin.2020.117315
Wantana N., Kaewjaeng S., Kothan S. et al. // J. Lumin. 2017. V. 181. P. 382. https://doi.org/10.1016/j.jlumin.2016.09.050
He J., Zhang S., Zhou J. et al. // Opt. Mater. 2015. V. 39. P. 81. https://doi.org/10.1016/j.optmat.2014.11.002
Li Y., Dvořák M., Nesterenko P.N. et al. // Sens. Actuators B. 2018. V. 255. P. 1238. https://doi.org/10.1016/j.snb.2017.08.085
Kelly K.L. // J. Opt. Soc. Am. 1943. V. 33. P. 627. https://doi.org/10.1364/JOSA.33.000627