Indium Oxide–Graphene Composites Prepared by the Sol–Gel Process and Single-Electrode Gas Sensors on Their Base
- Authors: Haiduk Y.S.1, Usenka A.E.1, Rutkovskaya L.S.1, Golodok R.P.2, Timonenkova A.S.1, Pankov V.V.1
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Affiliations:
- Belarussian State University
- Academician Roman Institute of Powder Metallurgy, National Academy of Sciences of the Republic of Belarus
- Issue: Vol 68, No 1 (2023)
- Pages: 145-154
- Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
- URL: https://journals.rcsi.science/0044-457X/article/view/136315
- DOI: https://doi.org/10.31857/S0044457X22601365
- EDN: https://elibrary.ru/GWAMEI
- ID: 136315
Cite item
Abstract
Indium oxide–graphene composites (containing 0–6.0 wt % graphene) were manufactured by the sol–gel process. The phase composition, microstructure, and gas-sensitive properties of the prepared materials were studied. The composites consist of isolated In2O3 and graphene phases, where graphene is predominantly adsorbed on the surfaces of indium oxide grains (the indium oxide grain sizes are 8–11 nm). The nanocomposites are distinguished by an enhanced sensitivity to both reducing gases (CH4, acetone) and oxidative gases (NO2). A far greater enhancement is in the sensory response to oxidative gases. Presumably, the major factors influencing the sensory properties of the composite are the high defectiveness of In2O3 and graphene phases, higher specific surface areas of composites compared to those of individual In2O3, and the likely formation of p–n junctions in the indium oxide and graphene contact zone. Graphene additives to indium oxide can improve the main performances (sensory response, response time, and recovery time) of single-electrode semiconductor sensors.
About the authors
Yu. S. Haiduk
Belarussian State University
Email: haidukys@bsu.by
220030, Minsk, Belarus
A. E. Usenka
Belarussian State University
Email: haidukys@bsu.by
220030, Minsk, Belarus
L. S. Rutkovskaya
Belarussian State University
Email: haidukys@bsu.by
220030, Minsk, Belarus
R. P. Golodok
Academician Roman Institute of Powder Metallurgy, National Academy of Sciences of the Republic of Belarus
Email: haidukys@bsu.by
220072, Minsk, Belarus
A. S. Timonenkova
Belarussian State University
Email: haidukys@bsu.by
220030, Minsk, Belarus
V. V. Pankov
Belarussian State University
Author for correspondence.
Email: haidukys@bsu.by
220030, Minsk, Belarus
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