Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

V. M. Zelikman; Зеликман В. М.; K. I. Maslakov; Маслаков К. И.; I. A. Ivanin; Иванин И. А.; I. G. Tarkhanova; Тарханова И. Г.

doi:10.31857/S0044453723090273

Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

Authors: Zelikman V.M.¹, Maslakov K.I.¹, Ivanin I.A.¹, Tarkhanova I.G.¹
Affiliations:
1. Faculty of Chemistry, Moscow State University
Issue: Vol 97, No 9 (2023)
Pages: 1239-1247
Section: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
URL: https://journals.rcsi.science/0044-4537/article/view/136648
DOI: https://doi.org/10.31857/S0044453723090273
EDN: https://elibrary.ru/XQBDHD
ID: 136648

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Abstract
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Abstract

A set of silica gel-immobilized compounds is synthesized that consists of ethylimidazole cations and anions of phosphotungstic acid (lacunar (PW11) or mixed (PW11M), where M = Zn, Ni, Cu, Co, Mn). The composition and textural characteristics of the compounds are determined by physicochemical means (IR spectroscopy, XPS, SEM/EDX, adsorption). The synthesized heterogeneous composites are active in the oxidation of sulfur- and nitrogen-containing components of petroleum feedstocks with hydrogen peroxide. A comparative analysis is performed of the samples’ catalytic properties in the oxidation of both individual substrates (thiophene, dibenzothiophene, methyl phenyl sulfide, pyridine) and their mixtures.

Keywords

oxidative desulfurization, oxidative denitrogenation, polyoxometalates, immobilized catalysts

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