Enviar artigo por via de e-mail Investigation of Physicochemical Characteristics of Lead Dioxide Coatings to Enhance the Performance of Reserve Quickly Activated Chemical Power Sources in the Lead–Perchloric Acid–Lead Dioxide System
- Autores: Shcheglov P.1, Samsonov D.1, Pavlenkov A.1, Kulova T.2, Rychagov A.2, Andreev V.3, Skundin A.2
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Afiliações:
- Scientific and Production Association “Pribor” named after S.S. Golembiovsky
- A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Investigation of Physicochemical Characteristics of Lead Dioxide Coatings to Enhance the Performance of Reserve Quickly Activated Chemical Power Sources in the Lead–Perchloric Acid–Lead Dioxide System
- Edição: Volume 97, Nº 12 (2023)
- Páginas: 1783-1793
- Seção: ЭЛЕКТРОХИМИЯ. ГЕНЕРАЦИЯ И АККУМУЛИРОВАНИЕ ЭНЕРГИИ ИЗ ВОЗОБНОВЛЯЕМЫХ ИСТОЧНИКОВ
- URL: https://journals.rcsi.science/0044-4537/article/view/233075
- DOI: https://doi.org/10.31857/S0044453723120269
- EDN: https://elibrary.ru/JGTRRF
- ID: 233075
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Resumo
The relationship between the discharge characteristics of reserve chemical power sources of the lead–perchloric acid–lead dioxide system and the physicochemical properties of electroplated cathode coatings with lead dioxide, including phase composition and microstructure, has been studied. The study reveals that the discharge characteristics of power sources can be enhanced by employing a two-layer lead dioxide coating consisting of a porous outer layer and a denser inner layer. The findings have been validated through the production and testing of industrial prototypes of pilot miniature reserve power sources, which exhibit improved performance even at low temperatures (activation time, less than 30 ms; discharge capacity, ~200 mA min/cm2; discharge voltage per cell, 1.8–1.2 V at –50°C).
Sobre autores
P. Shcheglov
Scientific and Production Association “Pribor” named after S.S. Golembiovsky
Email: tkulova@mail.ru
117587, Moscow, Russia
D. Samsonov
Scientific and Production Association “Pribor” named after S.S. Golembiovsky
Email: d@samsonov-work.ru
119071, Moscow, Russia
A. Pavlenkov
Scientific and Production Association “Pribor” named after S.S. Golembiovsky
Email: tkulova@mail.ru
117587, Moscow, Russia
T. Kulova
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: tkulova@mail.ru
119071, Moscow, Russia
A. Rychagov
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: tkulova@mail.ru
119071, Moscow, Russia
V. Andreev
Investigation of Physicochemical Characteristics of Lead Dioxide Coatings to Enhance the Performance of Reserve Quickly Activated Chemical Power Sources in the Lead–Perchloric Acid–Lead Dioxide System
Email: tkulova@mail.ru
119071, Moscow, Russia
A. Skundin
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Autor responsável pela correspondência
Email: tkulova@mail.ru
119071, Moscow, Russia
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