The Development of a Method for the Production of Structural Polymeric Materials on the Basis of Norbornene Derivatives


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Abstract

Process parameters of the polymerization of a mixture of exo,exo- and endo,endo-dimethyl esters of norbornene-2,3-dicarboxylic acid in the bulk of the monomer under the action of a ruthenium catalyst of the Hoveyda–Grubbs type are developed. The effect of the concentration of the catalyst on the physical and mechanical properties of poly(norbornene-2,3-dicarboxylic acid dimethyl ester) is studied.

About the authors

G. S. Bozhenkova

National Research Tomsk Polytechnic University

Author for correspondence.
Email: bozhenkova@sibmail.com
Russian Federation, Tomsk, 634050

N. A. Smirnova

National Research Tomsk Polytechnic University

Email: bozhenkova@sibmail.com
Russian Federation, Tomsk, 634050

O. O. Bragina

National Research Tomsk Polytechnic University

Email: bozhenkova@sibmail.com
Russian Federation, Tomsk, 634050

R. V. Ashirov

AO Polyus

Email: bozhenkova@sibmail.com
Russian Federation, Krasnoyarsk, 663282

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