The Development of a Method for the Production of Structural Polymeric Materials on the Basis of Norbornene Derivatives

G. S. Bozhenkova; N. A. Smirnova; O. O. Bragina; R. V. Ashirov

doi:10.1134/S0040579518050068

The Development of a Method for the Production of Structural Polymeric Materials on the Basis of Norbornene Derivatives

作者: Bozhenkova G.S.¹, Smirnova N.A.¹, Bragina O.O.¹, Ashirov R.V.²
隶属关系:
1. National Research Tomsk Polytechnic University
2. AO Polyus
期: 卷 53, 编号 5 (2019)
页面: 875-879
栏目: Technology of Polymeric and Composite Materials
URL: https://journals.rcsi.science/0040-5795/article/view/173138
DOI: https://doi.org/10.1134/S0040579518050068
ID: 173138

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详细

Process parameters of the polymerization of a mixture of exo,exo- and endo,endo-dimethyl esters of norbornene-2,3-dicarboxylic acid in the bulk of the monomer under the action of a ruthenium catalyst of the Hoveyda–Grubbs type are developed. The effect of the concentration of the catalyst on the physical and mechanical properties of poly(norbornene-2,3-dicarboxylic acid dimethyl ester) is studied.