Simulation of continuous packed bed reactive distillation column for the esterification process using activity based kinetic model

Abstract

A mathematical model for the continuous packed bed reactive distillation process of esterification of acetic acid with methanol is developed. The kinetic rate equation, which plays a major role for the performance of reactive distillation and it is the part of model, is required for the liquid phase reversible esterification reaction. The mineral sulphuric acid is used as the catalyst. The kinetic experiments are carried out under different temperatures in the range of 305.15 to 333.15 K and catalyst concentrations in the range of 0.1267 mole H⁺/lit to 0.6537 mole H⁺/lit. From that experimental data the kinetic model is developed and the same is used for the simulation of reactive distillation process. Equilibrium stage model, in which the vapour and the liquid leaving a stage are assumed to be in equilibrium with each other, has been used for the simulation of reactive distillation process by incorporating our kinetic model. Conversion of acetic acid as function of reflux ratio and reboiler ratio has been predicted. The liquid composition and temperature profiles versus stage number have been also predicted. Finally, the optimum operating conditions obtained from the simulation results for high pure methyl acetate by reactive distillation process.