Enviar artigo por via de e-mail Mechanism and Caloric Effects of the Thermal Dehydration of GdCl3 ⋅ 6H2O Crystalline Hydrate
- Autores: Korzun I.V.1, Zakir’yanova I.D.1,2, Nikolaeva E.V.1,2
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Afiliações:
- Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
- Ural Federal University
- Edição: Volume 2018, Nº 8 (2018)
- Páginas: 722-727
- Seção: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/172033
- DOI: https://doi.org/10.1134/S0036029518080104
- ID: 172033
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Resumo
Abstract—The thermal dehydration of GdCl3 ⋅ 6H2O crystalline hydrate is studied by synchronous thermal analysis and mass spectrometry using certified samples. The mechanism and the caloric effects of the chemical reactions are determined. The thermal decomposition of GdCl3 ⋅ 6H2O crystalline hydrate is accompanied by hydrolysis, leading to the formation of oxychloride GdOCl.
Sobre autores
I. Korzun
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Email: optica96@ihte.uran.ru
Rússia, Yekaterinburg, 620000
I. Zakir’yanova
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Autor responsável pela correspondência
Email: optica96@ihte.uran.ru
Rússia, Yekaterinburg, 620000; Yekaterinburg, 620002
E. Nikolaeva
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Email: optica96@ihte.uran.ru
Rússia, Yekaterinburg, 620000; Yekaterinburg, 620002
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