Mechanism and Caloric Effects of the Thermal Dehydration of GdCl 3  ⋅ 6H 2 O Crystalline Hydrate

I. V. Korzun; I. D. Zakir’yanova; E. V. Nikolaeva

doi:10.1134/S0036029518080104

Mechanism and Caloric Effects of the Thermal Dehydration of GdCl₃ ⋅ 6H₂O Crystalline Hydrate

作者: Korzun I.¹, Zakir’yanova I.¹^,2, Nikolaeva E.¹^,2
隶属关系:
1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
2. Ural Federal University
期: 卷 2018, 编号 8 (2018)
页面: 722-727
栏目: Article
URL: https://journals.rcsi.science/0036-0295/article/view/172033
DOI: https://doi.org/10.1134/S0036029518080104
ID: 172033

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详细

Abstract—The thermal dehydration of GdCl₃ ⋅ 6H₂O crystalline hydrate is studied by synchronous thermal analysis and mass spectrometry using certified samples. The mechanism and the caloric effects of the chemical reactions are determined. The thermal decomposition of GdCl₃ ⋅ 6H₂O crystalline hydrate is accompanied by hydrolysis, leading to the formation of oxychloride GdOCl.

关键词

dehydration, crystalline hydrate, gadolinium chloride, synchronous thermal analysis, mass spectrometry

作者简介

I. Korzun

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences

Email: optica96@ihte.uran.ru
俄罗斯联邦, Yekaterinburg, 620000

I. Zakir’yanova

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University

编辑信件的主要联系方式.
Email: optica96@ihte.uran.ru
俄罗斯联邦, Yekaterinburg, 620000; Yekaterinburg, 620002

E. Nikolaeva