Anomalies of the Thermodynamic Parameters of the Heterogeneous Li2CO3–Na2CO3–K2CO3–MgO Nanopowder System


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Abstract

The thermodynamic parameters of the heterogeneous Li2CO3–Na2CO3–K2CO3–MgO nanopowder system are detemined by differential scanning calorimetry (DSC). The melting temperature and the reduced enthalpy of melting of the salt phase are found to decrease anomalously as the magnesium oxide content in the composite material increases.

About the authors

I. D. Zakir’yanova

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University

Author for correspondence.
Email: optica96@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000; Yekaterinburg, 620002

I. V. Korzun

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences

Email: optica96@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000


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