Kinetics of metal exchange in Cd(II) octa(4-bromophenyl)porphyrinate with d-metal salts in organic solvents
- 作者: Zvezdina S.1, Chizhova N.1, Mamardashvili N.1
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隶属关系:
- Krestov Institute of Solution Chemistry
- 期: 卷 91, 编号 3 (2017)
- 页面: 437-441
- 栏目: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169302
- DOI: https://doi.org/10.1134/S0036024417030335
- ID: 169302
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详细
The reaction of metal exchange between Cd(II) octa(4-bromophenyl)porphyrinate with СuCl2 and ZnCl2 in DMFA and DMSO is studied by means of spectrophotometry. The kinetic parameters of the metal exchange reaction are calculated, a stoichiometric reaction mechanism is proposed. The effect the natures of the solvent, salt solvate, and the chemical modification of tetrapyrrole macrocycle have on the kinetic parameters of the metal exchange reaction are revealed.
作者简介
S. Zvezdina
Krestov Institute of Solution Chemistry
编辑信件的主要联系方式.
Email: svvr@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045
N. Chizhova
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045
N. Mamardashvili
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045