Kinetics of metal exchange in Cd(II) octa(4-bromophenyl)porphyrinate with d-metal salts in organic solvents
- Авторы: Zvezdina S.V.1, Chizhova N.V.1, Mamardashvili N.Z.1
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Учреждения:
- Krestov Institute of Solution Chemistry
- Выпуск: Том 91, № 3 (2017)
- Страницы: 437-441
- Раздел: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169302
- DOI: https://doi.org/10.1134/S0036024417030335
- ID: 169302
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Аннотация
The reaction of metal exchange between Cd(II) octa(4-bromophenyl)porphyrinate with СuCl2 and ZnCl2 in DMFA and DMSO is studied by means of spectrophotometry. The kinetic parameters of the metal exchange reaction are calculated, a stoichiometric reaction mechanism is proposed. The effect the natures of the solvent, salt solvate, and the chemical modification of tetrapyrrole macrocycle have on the kinetic parameters of the metal exchange reaction are revealed.
Об авторах
S. Zvezdina
Krestov Institute of Solution Chemistry
Автор, ответственный за переписку.
Email: svvr@isc-ras.ru
Россия, Ivanovo, 153045
N. Chizhova
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Россия, Ivanovo, 153045
N. Mamardashvili
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Россия, Ivanovo, 153045
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