Kinetic characteristics of gas–liquid ozone reactions
- Авторы: Levanov A.1, Isaikina O.1,2, Lunin V.1,2
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Учреждения:
- Faculty of Chemistry
- Topchiev Institute of Petrochemical Synthesis
- Выпуск: Том 91, № 10 (2017)
- Страницы: 1845-1850
- Раздел: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169714
- DOI: https://doi.org/10.1134/S0036024417100235
- ID: 169714
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Аннотация
An experimental chemical method for determining the kinetic characteristics (volumetric mass transfer coefficient and rate constant of a second-order reaction) of gas–liquid ozone reactions in a bubble column reactor is described. The calculation formulas are substantiated, and the ranges of values of the experimental factors that determine the method’s limits of applicability are found. The conditions under which the boundary-value problem of a gas–liquid ozone reaction of the second order can be reduced to a problem of a pseudo-first order reaction allowing an analytical solution are revealed.
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Об авторах
A. Levanov
Faculty of Chemistry
Автор, ответственный за переписку.
Email: levanov@kge.msu.ru
Россия, Moscow, 119991
O. Isaikina
Faculty of Chemistry; Topchiev Institute of Petrochemical Synthesis
Email: levanov@kge.msu.ru
Россия, Moscow, 119991; Moscow, 119991
V. Lunin
Faculty of Chemistry; Topchiev Institute of Petrochemical Synthesis
Email: levanov@kge.msu.ru
Россия, Moscow, 119991; Moscow, 119991