Email this article Kinetic characteristics of gas–liquid ozone reactions
- Authors: Levanov A.V.1, Isaikina O.Y.1,2, Lunin V.V.1,2
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Affiliations:
- Faculty of Chemistry
- Topchiev Institute of Petrochemical Synthesis
- Issue: Vol 91, No 10 (2017)
- Pages: 1845-1850
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169714
- DOI: https://doi.org/10.1134/S0036024417100235
- ID: 169714
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Abstract
An experimental chemical method for determining the kinetic characteristics (volumetric mass transfer coefficient and rate constant of a second-order reaction) of gas–liquid ozone reactions in a bubble column reactor is described. The calculation formulas are substantiated, and the ranges of values of the experimental factors that determine the method’s limits of applicability are found. The conditions under which the boundary-value problem of a gas–liquid ozone reaction of the second order can be reduced to a problem of a pseudo-first order reaction allowing an analytical solution are revealed.
About the authors
A. V. Levanov
Faculty of Chemistry
Author for correspondence.
Email: levanov@kge.msu.ru
Russian Federation, Moscow, 119991
O. Ya. Isaikina
Faculty of Chemistry; Topchiev Institute of Petrochemical Synthesis
Email: levanov@kge.msu.ru
Russian Federation, Moscow, 119991; Moscow, 119991
V. V. Lunin
Faculty of Chemistry; Topchiev Institute of Petrochemical Synthesis
Email: levanov@kge.msu.ru
Russian Federation, Moscow, 119991; Moscow, 119991
