Enviar artigo por via de e-mail Kinetics of metal exchange in Cd(II) octa(4-bromophenyl)porphyrinate with d-metal salts in organic solvents
- Autores: Zvezdina S.1, Chizhova N.1, Mamardashvili N.1
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Afiliações:
- Krestov Institute of Solution Chemistry
- Edição: Volume 91, Nº 3 (2017)
- Páginas: 437-441
- Seção: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169302
- DOI: https://doi.org/10.1134/S0036024417030335
- ID: 169302
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Resumo
The reaction of metal exchange between Cd(II) octa(4-bromophenyl)porphyrinate with СuCl2 and ZnCl2 in DMFA and DMSO is studied by means of spectrophotometry. The kinetic parameters of the metal exchange reaction are calculated, a stoichiometric reaction mechanism is proposed. The effect the natures of the solvent, salt solvate, and the chemical modification of tetrapyrrole macrocycle have on the kinetic parameters of the metal exchange reaction are revealed.
Sobre autores
S. Zvezdina
Krestov Institute of Solution Chemistry
Autor responsável pela correspondência
Email: svvr@isc-ras.ru
Rússia, Ivanovo, 153045
N. Chizhova
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Rússia, Ivanovo, 153045
N. Mamardashvili
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Rússia, Ivanovo, 153045
