Enviar artigo por via de e-mail Rhodium Catalyst–Ionic Liquids Interaction by X-ray Photoelectron Spectroscopy Data
- Autores: Yujuan Jin 1, Shuang Men 2
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Afiliações:
- School of Materials and Mechanical Engineering Beijing Technology and Business University
- School of Material Science and Engineering Shenyang Ligong University
- Edição: Volume 92, Nº 12 (2018)
- Páginas: 2472-2475
- Seção: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/170251
- DOI: https://doi.org/10.1134/S0036024418120361
- ID: 170251
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Resumo
We investigate the Schrock–Osborn catalyst, [Rh(COD)(PPh3)2][PF6], in a series of ionic liquids by XPS. The electronic environment of the rhodium centre is demonstrated. The subtle change of the electronic environment of the rhodium centre due to the catalyst-ionic liquids interaction is revealed based upon Rh 3d binding energy. It suggests that the anion of ionic liquids can have significant impact on the electronic environment of the rhodium centre.
Sobre autores
Yujuan Jin
School of Materials and Mechanical Engineering Beijing Technology and Business University
Autor responsável pela correspondência
Email: jinyujuan@th.btbu.edu.cn
República Popular da China, Beijing
Shuang Men
School of Material Science and Engineering Shenyang Ligong University
Email: jinyujuan@th.btbu.edu.cn
República Popular da China, Shenyang
