Email this article Rhodium Catalyst–Ionic Liquids Interaction by X-ray Photoelectron Spectroscopy Data
- Authors: Yujuan Jin 1, Shuang Men 2
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Affiliations:
- School of Materials and Mechanical Engineering Beijing Technology and Business University
- School of Material Science and Engineering Shenyang Ligong University
- Issue: Vol 92, No 12 (2018)
- Pages: 2472-2475
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/170251
- DOI: https://doi.org/10.1134/S0036024418120361
- ID: 170251
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Abstract
We investigate the Schrock–Osborn catalyst, [Rh(COD)(PPh3)2][PF6], in a series of ionic liquids by XPS. The electronic environment of the rhodium centre is demonstrated. The subtle change of the electronic environment of the rhodium centre due to the catalyst-ionic liquids interaction is revealed based upon Rh 3d binding energy. It suggests that the anion of ionic liquids can have significant impact on the electronic environment of the rhodium centre.
About the authors
Yujuan Jin
School of Materials and Mechanical Engineering Beijing Technology and Business University
Author for correspondence.
Email: jinyujuan@th.btbu.edu.cn
China, Beijing
Shuang Men
School of Material Science and Engineering Shenyang Ligong University
Email: jinyujuan@th.btbu.edu.cn
China, Shenyang
