Мақаланы E-mail арқылы жіберу Rhodium Catalyst–Ionic Liquids Interaction by X-ray Photoelectron Spectroscopy Data
- Авторлар: Yujuan Jin 1, Shuang Men 2
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Мекемелер:
- School of Materials and Mechanical Engineering Beijing Technology and Business University
- School of Material Science and Engineering Shenyang Ligong University
- Шығарылым: Том 92, № 12 (2018)
- Беттер: 2472-2475
- Бөлім: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/170251
- DOI: https://doi.org/10.1134/S0036024418120361
- ID: 170251
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Рұқсат берілді
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Аннотация
We investigate the Schrock–Osborn catalyst, [Rh(COD)(PPh3)2][PF6], in a series of ionic liquids by XPS. The electronic environment of the rhodium centre is demonstrated. The subtle change of the electronic environment of the rhodium centre due to the catalyst-ionic liquids interaction is revealed based upon Rh 3d binding energy. It suggests that the anion of ionic liquids can have significant impact on the electronic environment of the rhodium centre.
Авторлар туралы
Yujuan Jin
School of Materials and Mechanical Engineering Beijing Technology and Business University
Хат алмасуға жауапты Автор.
Email: jinyujuan@th.btbu.edu.cn
ҚХР, Beijing
Shuang Men
School of Material Science and Engineering Shenyang Ligong University
Email: jinyujuan@th.btbu.edu.cn
ҚХР, Shenyang
