Metastable Equilibria with the Participation of Superheated Crystal Phases in Binary Oxide Systems
- Autores: Kosyakov V.1, Shestakov V.1,2, Kaplun A.3, Meshalkin A.3
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Afiliações:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University of Architecture and Civil Engineering
- Kutateladze Institute of Thermophysics, Siberian Branch
- Edição: Volume 90, Nº 4 (2016)
- Páginas: 718-722
- Seção: Chemical Thermodynamics and Thermochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/167985
- DOI: https://doi.org/10.1134/S0036024416040142
- ID: 167985
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Resumo
Experimental diagrams of binary systems, including compounds that melt upon decomposition, sometimes display the metastable congruent melting of such compounds above the peritectic equilibrium temperature. Conditions in which the occurrence of superheated states of binary systems is possible are analyzed. Thermodynamic and kinetic interpretations of such phenomena are presented.
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Sobre autores
V. Kosyakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Autor responsável pela correspondência
Email: vsh@niic.nsc.ru
Rússia, Novosibirsk, 630090
V. Shestakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University of Architecture and Civil Engineering
Email: vsh@niic.nsc.ru
Rússia, Novosibirsk, 630090; Novosibirsk, 630008
A. Kaplun
Kutateladze Institute of Thermophysics, Siberian Branch
Email: vsh@niic.nsc.ru
Rússia, Novosibirsk, 630090
A. Meshalkin
Kutateladze Institute of Thermophysics, Siberian Branch
Email: vsh@niic.nsc.ru
Rússia, Novosibirsk, 630090