Email this article Metastable Equilibria with the Participation of Superheated Crystal Phases in Binary Oxide Systems
- Authors: Kosyakov V.I.1, Shestakov V.A.1,2, Kaplun A.B.3, Meshalkin A.B.3
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University of Architecture and Civil Engineering
- Kutateladze Institute of Thermophysics, Siberian Branch
- Issue: Vol 90, No 4 (2016)
- Pages: 718-722
- Section: Chemical Thermodynamics and Thermochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/167985
- DOI: https://doi.org/10.1134/S0036024416040142
- ID: 167985
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Abstract
Experimental diagrams of binary systems, including compounds that melt upon decomposition, sometimes display the metastable congruent melting of such compounds above the peritectic equilibrium temperature. Conditions in which the occurrence of superheated states of binary systems is possible are analyzed. Thermodynamic and kinetic interpretations of such phenomena are presented.
Keywords
About the authors
V. I. Kosyakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: vsh@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
V. A. Shestakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University of Architecture and Civil Engineering
Email: vsh@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630008
A. B. Kaplun
Kutateladze Institute of Thermophysics, Siberian Branch
Email: vsh@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
A. B. Meshalkin
Kutateladze Institute of Thermophysics, Siberian Branch
Email: vsh@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
