Thermodynamic properties and amorphization of Zr–Si melts
- Autores: Arutyunyan N.1, Zaitsev A.1,2, Dunaev S.1, Shaposhnikov N.1
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Afiliações:
- Department of Chemistry
- Bardin Central Research Institute of Ferrous Metals
- Edição: Volume 90, Nº 2 (2016)
- Páginas: 257-262
- Seção: Chemical Thermodynamics and Thermochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/167666
- DOI: https://doi.org/10.1134/S0036024416020059
- ID: 167666
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Resumo
The relationship between the thermodynamic properties of Zr–Si liquid alloys and their propensity to amorphization is studied. The temperature–concentration dependences of the thermodynamic properties of melts are presented using the concept of associated solutions. It is shown that the range of amorphization coincides with the range of the predominant concentration of Zr3Si associative groups with low formation entropy.
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Sobre autores
N. Arutyunyan
Department of Chemistry
Autor responsável pela correspondência
Email: naarutyunyan@rambler.ru
Rússia, Moscow, 119991
A. Zaitsev
Department of Chemistry; Bardin Central Research Institute of Ferrous Metals
Email: naarutyunyan@rambler.ru
Rússia, Moscow, 119991; Moscow, 105005
S. Dunaev
Department of Chemistry
Email: naarutyunyan@rambler.ru
Rússia, Moscow, 119991
N. Shaposhnikov
Department of Chemistry
Email: naarutyunyan@rambler.ru
Rússia, Moscow, 119991