Email this article Thermodynamic properties and amorphization of Zr–Si melts
- Authors: Arutyunyan N.A.1, Zaitsev A.I.1,2, Dunaev S.F.1, Shaposhnikov N.G.1
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Affiliations:
- Department of Chemistry
- Bardin Central Research Institute of Ferrous Metals
- Issue: Vol 90, No 2 (2016)
- Pages: 257-262
- Section: Chemical Thermodynamics and Thermochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/167666
- DOI: https://doi.org/10.1134/S0036024416020059
- ID: 167666
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Abstract
The relationship between the thermodynamic properties of Zr–Si liquid alloys and their propensity to amorphization is studied. The temperature–concentration dependences of the thermodynamic properties of melts are presented using the concept of associated solutions. It is shown that the range of amorphization coincides with the range of the predominant concentration of Zr3Si associative groups with low formation entropy.
About the authors
N. A. Arutyunyan
Department of Chemistry
Author for correspondence.
Email: naarutyunyan@rambler.ru
Russian Federation, Moscow, 119991
A. I. Zaitsev
Department of Chemistry; Bardin Central Research Institute of Ferrous Metals
Email: naarutyunyan@rambler.ru
Russian Federation, Moscow, 119991; Moscow, 105005
S. F. Dunaev
Department of Chemistry
Email: naarutyunyan@rambler.ru
Russian Federation, Moscow, 119991
N. G. Shaposhnikov
Department of Chemistry
Email: naarutyunyan@rambler.ru
Russian Federation, Moscow, 119991
