Conditions for the Formation of Microporous Metal–Organic Framework Mil-53(Al)
- Авторлар: Isaeva V.1,2, Chernyshev V.3,4, Tarasov A.1,2, Lobova A.3, Kapustin G.1, Davshan N.1
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Мекемелер:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- National University of Science and Technology (MISiS)
- Department of Chemistry, Moscow State University
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Шығарылым: Том 92, № 12 (2018)
- Беттер: 2386-2390
- Бөлім: Physical Chemistry of Hybrid Nanomaterials and Multicomponent Systems
- URL: https://journals.rcsi.science/0036-0244/article/view/170236
- DOI: https://doi.org/10.1134/S0036024418120166
- ID: 170236
Дәйексөз келтіру
Аннотация
Conditions of crystallization are determined for the MIL-53 (Al) (AlOHbdc, bdc = benzene-1,4-dicarboxylate) microporous metal–organic framework. Three major factors responsible for the formation of a pure phase of MIL-53(Al) are identified. These include the temperature (above ~120°С) and the nature of the solvent. It is established through powder diffraction that using microwave radiation for the activation of the reaction mass leads to the formation of a material with higher phase purity, in contrast to preparation techniques that employ conventional heating (hydrothermal synthesis and synthesis under atmospheric pressure).
Авторлар туралы
V. Isaeva
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; National University of Science and Technology (MISiS)
Хат алмасуға жауапты Автор.
Email: sharf@ioc.ac.ru
Ресей, Moscow, 119991; Moscow, 119991
V. Chernyshev
Department of Chemistry, Moscow State University; Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: vladimir@struct.chem.msu.ru
Ресей, Moscow, 119234; Moscow, 119071
A. Tarasov
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; National University of Science and Technology (MISiS)
Email: vladimir@struct.chem.msu.ru
Ресей, Moscow, 119991; Moscow, 119991
A. Lobova
Department of Chemistry, Moscow State University
Email: vladimir@struct.chem.msu.ru
Ресей, Moscow, 119234
G. Kapustin
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
Ресей, Moscow, 119991
N. Davshan
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
Ресей, Moscow, 119991