Conditions for the Formation of Microporous Metal–Organic Framework Mil-53(Al)
- 作者: Isaeva V.1,2, Chernyshev V.3,4, Tarasov A.1,2, Lobova A.3, Kapustin G.1, Davshan N.1
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隶属关系:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- National University of Science and Technology (MISiS)
- Department of Chemistry, Moscow State University
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- 期: 卷 92, 编号 12 (2018)
- 页面: 2386-2390
- 栏目: Physical Chemistry of Hybrid Nanomaterials and Multicomponent Systems
- URL: https://journals.rcsi.science/0036-0244/article/view/170236
- DOI: https://doi.org/10.1134/S0036024418120166
- ID: 170236
如何引用文章
详细
Conditions of crystallization are determined for the MIL-53 (Al) (AlOHbdc, bdc = benzene-1,4-dicarboxylate) microporous metal–organic framework. Three major factors responsible for the formation of a pure phase of MIL-53(Al) are identified. These include the temperature (above ~120°С) and the nature of the solvent. It is established through powder diffraction that using microwave radiation for the activation of the reaction mass leads to the formation of a material with higher phase purity, in contrast to preparation techniques that employ conventional heating (hydrothermal synthesis and synthesis under atmospheric pressure).
作者简介
V. Isaeva
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; National University of Science and Technology (MISiS)
编辑信件的主要联系方式.
Email: sharf@ioc.ac.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991
V. Chernyshev
Department of Chemistry, Moscow State University; Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences
编辑信件的主要联系方式.
Email: vladimir@struct.chem.msu.ru
俄罗斯联邦, Moscow, 119234; Moscow, 119071
A. Tarasov
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; National University of Science and Technology (MISiS)
Email: vladimir@struct.chem.msu.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991
A. Lobova
Department of Chemistry, Moscow State University
Email: vladimir@struct.chem.msu.ru
俄罗斯联邦, Moscow, 119234
G. Kapustin
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
俄罗斯联邦, Moscow, 119991
N. Davshan
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
俄罗斯联邦, Moscow, 119991