Отправить статью по E-mail Complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with nickel nitrate in acetone
- Авторы: Zhiltsova E.P.1, Lukashenko S.S.1, Ibatullina M.R.1,2, Kutyreva M.P.2, Zakharova L.Y.1
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Учреждения:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Kazan Federal University
- Выпуск: Том 90, № 7 (2016)
- Страницы: 1374-1378
- Раздел: Structure of Matter and Quantum Chemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/168446
- DOI: https://doi.org/10.1134/S0036024416070359
- ID: 168446
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Аннотация
The complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with Ni(II) nitrate in acetone is studied by means of spectrophotometry (the Job–Ostromisslensky technique and molar ratios). The formation of 3: 1 and 1: 1 ligand: metal complexes is established and confirmed by mathematical modeling. The stability constants of the complexes and the change in the Gibbs free energy are determined.
Об авторах
E. Zhiltsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Автор, ответственный за переписку.
Email: Zhiltsova@iopc.ru
Россия, Kazan, 420088
S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Россия, Kazan, 420088
M. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan Federal University
Email: Zhiltsova@iopc.ru
Россия, Kazan, 420088; Kazan, 420008
M. Kutyreva
Kazan Federal University
Email: Zhiltsova@iopc.ru
Россия, Kazan, 420008
L. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Россия, Kazan, 420088
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