Thermodynamic properties of LiCl solutions in  N -methylacetamide at 308.15–328.15 K

N. G. Manin; A. M. Kolker

doi:10.1134/S0036024417120184

Thermodynamic properties of LiCl solutions in N-methylacetamide at 308.15–328.15 K

Authors: Manin N.G.¹, Kolker A.M.¹
Affiliations:
1. Krestov Institute of Solution Chemistry
Issue: Vol 91, No 12 (2017)
Pages: 2293-2301
Section: Chemical Thermodynamics and Thermochemistry
URL: https://journals.rcsi.science/0036-0244/article/view/169788
DOI: https://doi.org/10.1134/S0036024417120184
ID: 169788

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Abstract
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Abstract

Enthalpies of dissolution of crystalline LiCl and enthalpies of dilution of LiCl solutions in N-methylacetamide (NMA) with electrolyte concentrations no greater than 0.32m are measured on an isoperibolic calorimeter at 308.15, 318.15, and 328.5 K. Standard enthalpies of the dissolution of LiCl in NMA are calculated at different temperatures. The thermodynamic properties of the solution and its components are calculated and analyzed in the investigated range of concentrations and temperatures.

Keywords

thermochemistry, enthalpy of dissolution and dilution, N-methylacetamide, LiCl, relative partial enthalpy and heat capacity

About the authors

N. G. Manin

Krestov Institute of Solution Chemistry

Email: amk@isc-ras.ru
Russian Federation, Ivanovo, 153045

A. M. Kolker