Email this article Platinum clusters supported on/in Dion–Jacobson phase HLaNb2O7 by topochemical method
- Authors: Zhang W.1,2, Luo C.1,2, Wang C.1,2,3, Cui Y.1,2, Tang K.3
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Affiliations:
- School of Chemistry and Materials Engineering
- Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment
- Department of Chemistry
- Issue: Vol 90, No 13 (2016)
- Pages: 2616-2618
- Section: Physical Chemistry of Nanoclusters and Nanomaterials
- URL: https://journals.rcsi.science/0036-0244/article/view/169126
- DOI: https://doi.org/10.1134/S0036024416130197
- ID: 169126
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Abstract
Platinum clusters were supported on/in HLaNb2O7 nanosheets by topochemical reaction strategy for the first time. The as-prepared samples were analyzed using ICP OES and characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, nitrogen adsorption–desorption isotherms and X-ray photoelectron spectroscopy. The results showed that HLaNb2O7 nanosheets were modified with platinum clusters with good monodispersity. The product was a mesoporous solid with broad pore size distribution and large surface area. The oxidation state of platinum was zero and the size of Pt clusters was only about 1–2 nm. This study provides a novel approach to support metal clusters on layered compounds.
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About the authors
Wenbao Zhang
School of Chemistry and Materials Engineering; Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment
Email: chw007@mail.ustc.edu.cn
China, Fuyang, 236037; Fuyang, 236037
Chunhua Luo
School of Chemistry and Materials Engineering; Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment
Email: chw007@mail.ustc.edu.cn
China, Fuyang, 236037; Fuyang, 236037
Caihua Wang
School of Chemistry and Materials Engineering; Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment; Department of Chemistry
Author for correspondence.
Email: chw007@mail.ustc.edu.cn
China, Fuyang, 236037; Fuyang, 236037; Hefei, 230026
Yumin Cui
School of Chemistry and Materials Engineering; Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment
Email: chw007@mail.ustc.edu.cn
China, Fuyang, 236037; Fuyang, 236037
Kaibin Tang
Department of Chemistry
Email: chw007@mail.ustc.edu.cn
China, Hefei, 230026
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