Email this article Oxidation of benzyl alcohol by K2FeO4 to benzaldehyde over zeolites
- Authors: Wang Y.1, Song H.1, Song H.2, Jin Z.2
-
Affiliations:
- Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering
- Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province
- Issue: Vol 90, No 10 (2016)
- Pages: 1931-1935
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168810
- DOI: https://doi.org/10.1134/S0036024416100290
- ID: 168810
Cite item
Open Access
Access granted
Subscription Access
Abstract
A novel and green procedure for benzaldehyde synthesis by potassium ferrate oxidation of benzyl alcohol employing zeolite catalysts was studied. The prepared oxidant was characterized by SEM and XRD. The catalytic activity of various solid catalysts was studied using benzyl alcohol as a model compound. USY was found to be a very efficient catalyst for this particular oxidation process. Benzaldehyde yields up to 96.0% could be obtained at the following optimal conditions: 0.2 mL of benzyl alcohol, 4 mmol of K2FeO4, 0.5 g of USY zeolite; 20 mL of cyclohexene, 0.3 mL of acetic acid (36 wt %), 30°C temperature, 4 h reaction time.
Keywords
About the authors
Yuan-Yuan Wang
Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering
Email: songhua2004@sina.com
China, Daqing, Heilongjing, 163318
Hua Song
Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering
Author for correspondence.
Email: songhua2004@sina.com
China, Daqing, Heilongjing, 163318
Hua-Lin Song
Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province
Email: songhua2004@sina.com
China, Mudanjiang, Heilongjing, 157011
Zai-Shun Jin
Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province
Email: songhua2004@sina.com
China, Mudanjiang, Heilongjing, 157011
