Oxidation of benzyl alcohol by K2FeO4 to benzaldehyde over zeolites
- 作者: Wang Y.1, Song H.1, Song H.2, Jin Z.2
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隶属关系:
- Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering
- Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province
- 期: 卷 90, 编号 10 (2016)
- 页面: 1931-1935
- 栏目: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168810
- DOI: https://doi.org/10.1134/S0036024416100290
- ID: 168810
如何引用文章
详细
A novel and green procedure for benzaldehyde synthesis by potassium ferrate oxidation of benzyl alcohol employing zeolite catalysts was studied. The prepared oxidant was characterized by SEM and XRD. The catalytic activity of various solid catalysts was studied using benzyl alcohol as a model compound. USY was found to be a very efficient catalyst for this particular oxidation process. Benzaldehyde yields up to 96.0% could be obtained at the following optimal conditions: 0.2 mL of benzyl alcohol, 4 mmol of K2FeO4, 0.5 g of USY zeolite; 20 mL of cyclohexene, 0.3 mL of acetic acid (36 wt %), 30°C temperature, 4 h reaction time.
作者简介
Yuan-Yuan Wang
Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering
Email: songhua2004@sina.com
中国, Daqing, Heilongjing, 163318
Hua Song
Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering
编辑信件的主要联系方式.
Email: songhua2004@sina.com
中国, Daqing, Heilongjing, 163318
Hua-Lin Song
Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province
Email: songhua2004@sina.com
中国, Mudanjiang, Heilongjing, 157011
Zai-Shun Jin
Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province
Email: songhua2004@sina.com
中国, Mudanjiang, Heilongjing, 157011