电邮这篇文章 Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy
- 作者: Demina L.I.1,2, Kuz’mina L.G.2, Demin S.V.1,2, Shokurova N.A.1, Zhilov V.I.1,2, Tsivadze A.Y.1,2
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隶属关系:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- 期: 卷 62, 编号 11 (2017)
- 页面: 1536-1543
- 栏目: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0236/article/view/168193
- DOI: https://doi.org/10.1134/S0036023617110031
- ID: 168193
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详细
The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The complexes LiB15C5H2OX, where X = Cl− (1), I− (2), (3), (5), and LiBF4B15C5 (4) were synthesized and studied by IR spectroscopy. Complexes 1–4 were examined by X-ray diffraction. According to IR spectroscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted complex with the solvent was identified.
作者简介
L. Demina
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
俄罗斯联邦, Moscow, 119071; Moscow, 119991
L. Kuz’mina
Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
俄罗斯联邦, Moscow, 119991
S. Demin
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
俄罗斯联邦, Moscow, 119071; Moscow, 119991
N. Shokurova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
俄罗斯联邦, Moscow, 119071
V. Zhilov
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
编辑信件的主要联系方式.
Email: zhilov@igic.ras.ru
俄罗斯联邦, Moscow, 119071; Moscow, 119991
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
俄罗斯联邦, Moscow, 119071; Moscow, 119991
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