Enviar artigo por via de e-mail Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy
- Autores: Demina L.I.1,2, Kuz’mina L.G.2, Demin S.V.1,2, Shokurova N.A.1, Zhilov V.I.1,2, Tsivadze A.Y.1,2
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Afiliações:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Edição: Volume 62, Nº 11 (2017)
- Páginas: 1536-1543
- Seção: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0236/article/view/168193
- DOI: https://doi.org/10.1134/S0036023617110031
- ID: 168193
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Resumo
The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The complexes LiB15C5H2OX, where X = Cl− (1), I− (2), (3), (5), and LiBF4B15C5 (4) were synthesized and studied by IR spectroscopy. Complexes 1–4 were examined by X-ray diffraction. According to IR spectroscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted complex with the solvent was identified.
Sobre autores
L. Demina
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Rússia, Moscow, 119071; Moscow, 119991
L. Kuz’mina
Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Rússia, Moscow, 119991
S. Demin
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Rússia, Moscow, 119071; Moscow, 119991
N. Shokurova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Rússia, Moscow, 119071
V. Zhilov
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Autor responsável pela correspondência
Email: zhilov@igic.ras.ru
Rússia, Moscow, 119071; Moscow, 119991
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Rússia, Moscow, 119071; Moscow, 119991
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