Synthesis and Structure of Frame Xylaratogermanate Salts with Protonated Phenanthroline and Its Complexes with Fe(III) and Ni(II) as Cations
- Авторы: Chebanenko E.A.1, Seifullina I.I.1, Martsinko E.E.1, D’yakonenko V.V.2, Shishkina S.V.2,3
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Учреждения:
- Odessa National University
- Institute for Single Crystals, National Academy of Sciences of Ukraine
- Kharkov National University
- Выпуск: Том 64, № 9 (2019)
- Страницы: 1132-1137
- Раздел: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/169481
- DOI: https://doi.org/10.1134/S0036023619090043
- ID: 169481
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Аннотация
Synthesis procedures have been developed for new supramolecular xylaratogermanate salts with different cations: (HPhen)4[(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2] · 13H2O (I), [Fe(Phen)3]2[(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2] · 6H2O · C2H5OH (II), [Ni(Phen)3]2[(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2] · 8H2O (III). The compounds have been studied by X-ray diffraction, IR spectroscopy, and thermogravimetry. Their molecular and crystal structure has been determined. Compounds I–III include the same tetrameric μ-dihydroxyxylaratogermanate anion [(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2]4– with ditopic ligand, in which one of three hydroxyl groups does not coordinate to germanium(IV) but forms intramolecular hydrogen bond.
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Об авторах
E. Chebanenko
Odessa National University
Email: lborn@ukr.net
Украина, Odessa, 65082
I. Seifullina
Odessa National University
Email: lborn@ukr.net
Украина, Odessa, 65082
E. Martsinko
Odessa National University
Автор, ответственный за переписку.
Email: lborn@ukr.net
Украина, Odessa, 65082
V. D’yakonenko
Institute for Single Crystals, National Academy of Sciences of Ukraine
Email: lborn@ukr.net
Украина, Kharkov, 61072
S. Shishkina
Institute for Single Crystals, National Academy of Sciences of Ukraine; Kharkov National University
Email: lborn@ukr.net
Украина, Kharkov, 61072; Kharkov, 61072
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