Email this article Synthesis and Structure of Frame Xylaratogermanate Salts with Protonated Phenanthroline and Its Complexes with Fe(III) and Ni(II) as Cations
- Authors: Chebanenko E.A.1, Seifullina I.I.1, Martsinko E.E.1, D’yakonenko V.V.2, Shishkina S.V.2,3
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Affiliations:
- Odessa National University
- Institute for Single Crystals, National Academy of Sciences of Ukraine
- Kharkov National University
- Issue: Vol 64, No 9 (2019)
- Pages: 1132-1137
- Section: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/169481
- DOI: https://doi.org/10.1134/S0036023619090043
- ID: 169481
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Abstract
Synthesis procedures have been developed for new supramolecular xylaratogermanate salts with different cations: (HPhen)4[(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2] · 13H2O (I), [Fe(Phen)3]2[(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2] · 6H2O · C2H5OH (II), [Ni(Phen)3]2[(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2] · 8H2O (III). The compounds have been studied by X-ray diffraction, IR spectroscopy, and thermogravimetry. Their molecular and crystal structure has been determined. Compounds I–III include the same tetrameric μ-dihydroxyxylaratogermanate anion [(OH)2Ge2(µ-HXylar)4Ge2(µ-OH)2]4– with ditopic ligand, in which one of three hydroxyl groups does not coordinate to germanium(IV) but forms intramolecular hydrogen bond.
About the authors
E. A. Chebanenko
Odessa National University
Email: lborn@ukr.net
Ukraine, Odessa, 65082
I. I. Seifullina
Odessa National University
Email: lborn@ukr.net
Ukraine, Odessa, 65082
E. E. Martsinko
Odessa National University
Author for correspondence.
Email: lborn@ukr.net
Ukraine, Odessa, 65082
V. V. D’yakonenko
Institute for Single Crystals, National Academy of Sciences of Ukraine
Email: lborn@ukr.net
Ukraine, Kharkov, 61072
S. V. Shishkina
Institute for Single Crystals, National Academy of Sciences of Ukraine; Kharkov National University
Email: lborn@ukr.net
Ukraine, Kharkov, 61072; Kharkov, 61072
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