XPS determination of the oxidation state of 99Тс isotope absorbed on the surface of pirrhotite FenSn+1 and stibnite Sb2S3
- Autores: Maslakov K.1,2, Teterin A.2, Safonov A.3, Makarov A.3, Artemiev G.3, Teterin Y.1,2, Dvoriak S.1
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Afiliações:
- Lomonosov Moscow State University
- NRC “Kurchatov Institute”
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Edição: Volume 66, Nº 2 (2024)
- Páginas: 125–135
- Seção: Articles
- URL: https://journals.rcsi.science/0033-8311/article/view/263841
- DOI: https://doi.org/10.31857/S0033831124020039
- ID: 263841
Citar
Resumo
Sorption of pertechnetate on pyrrhotite FenSn+1 (I) and stibnite Sb2S3 (II) from distilled water was evaluated. The distribution coefficients were found to be 185 and 223 cm3/g, respectively. The XPS study of the chemical state of 99Tc absorbed on the surface of pyrrhotite and stibnite from aqueous solution of potassium pertechnetate (KTcO4) was carried out. It was found that Tc(IV) ions are present mostly on the surface of the studied samples, their concentration was 5.7 times higher on the surface of pyrrhotite compared to that on the surface of stibnite. A 13% admixture of Tc(VII) ions on the surface of pyrrhotite was observed.
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Sobre autores
K. Maslakov
Lomonosov Moscow State University; NRC “Kurchatov Institute”
Email: antonxray@yandex.ru
Radiochemistry Division, Chemistry Department
Rússia, Moscow; Kurchatov sq. 1, Moscow, 123182A. Teterin
NRC “Kurchatov Institute”
Autor responsável pela correspondência
Email: antonxray@yandex.ru
Rússia, Kurchatov sq. 1, Moscow, 123182
A. Safonov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: antonxray@yandex.ru
Rússia, Moscow
A. Makarov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: antonxray@yandex.ru
Rússia, Moscow
G. Artemiev
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: antonxray@yandex.ru
Rússia, Moscow
Yu. Teterin
Lomonosov Moscow State University; NRC “Kurchatov Institute”
Email: antonxray@yandex.ru
Radiochemistry Division, Chemistry Department
Rússia, Moscow; Kurchatov sq. 1, Moscow, 123182S. Dvoriak
Lomonosov Moscow State University
Email: antonxray@yandex.ru
Radiochemistry Division, Chemistry Department
Rússia, MoscowBibliografia
- Chatterjee S., Hall G.B., Jonson I.E., Du Y., Walter E.D., Washton N.M., Levitskaia T.G. // Inorg. Chem. Front. 2018. Vol. 5. P. 2081. https://doi.org/10.1039/C8QI00219C
- Meena A.H., Arai Y. // Environ. Chem. Lett. 2017. Vol. 15. N 2. P. 241–263. https://doi.org/10.1007/s10311-017-0605-7
- Garcia-Leon M. // J. Nucl. Radiochem. Sci. 2005. Vol. 6. N3. P. 253–259. https://doi.org/10.14494/jnrs2000.6.3_253
- Попова Н.Н., Тананаев И.Г., Ровный С.И., Мясоедов Б.Ф. // Успехи химии. 2003. Т. 72, № 2. С. 115–137. https://doi.org/10.1070/RC2003v072n02ABEH000785
- Makarov A.V., Safonov A.V., Konevnik Yu.V., Teterin Yu.A., Maslakov K.I., Teterin A. Yu. et al. // J. Hazard. Mater. 2021. Vol. 401. Article 123436 https://doi.org/10.1016/j.jhazmat.2020.123436
- Pegg I.L. // J. Radioanal. Nucl. Chem. 2015. Vol. 305. P. 287–292. https://doi.org/10.1007/s10967-014-3900-9
- Westsik J.H., Cantrell K.J., Serne R.J., Qafoku N.P. Technetium Immobilization Forms Literature Survey, PNNL-23329, EMSP-RPT-023 Pacific Northwest National Laboratory, Richland, WA, 2014. https://doi.org/10.2172/1130666
- Kamorny D.A., Safonov A.V., Boldyrev K.A., Abramova E.S., Tyupina E.A., Gorbunova O.A. // J. Nucl. Mater. 2021. Vol. 557. N 7. Article 153295. https://doi.org/10.1016/j.jnucmat.2021.153295
- Laverov N.P., Yudintsev S.V., Konovalov E.E., Mishevets T.O., Nikonov B.S., Omel’yanenko B.I. // Dokl. Chem. 2010. Vol. 431. P. 71–75. https://doi.org/10.1134/S0012500810030031
- Makarov A., Safonov A., Sitanskaia A., Martynov K., Zakharova E., Kulyukhin S. // Prog. Nucl. Energy. 2022. Vol. 152. Article 104398. https://doi.org/10.1016/j.pnucene.2022.104398
- Safonov A., Novikov A., Volkov M., Sitanskaia A., German K. // J. Radioanal. Nucl. Chem. 2023. Vol. 332. P. 2195–2204. https://doi.org/10.1007/s10967-023-08830-7
- Cantrell K.J., Williams B.D. // J. Nucl. Mater. 2013. V. 437, N 1–3. P. 424–431. https://doi.org/10.1016/j.jnucmat.2013.02.049
- May T., Matlack K.S., Muller I.S., Pegg I.L., Joseph I. Improved Technetium Retention in Hanford LAW Glass–Phase 1 Final Report. RPP-RPT-45887, Rev 0. Richland, WA: Washington River Protection Solutions, LLC.
- Um W., Chang H.S., Icenhower J.P., Lukens W.W., Serne R.J., Qafoku N. et al. // Environ. Sci. Technol. 2011. Vol. 45. N 11. P. 4904–4913. https://doi.org/10.1021/es104343p.
- Um W., Chang H.S., Icenhower J.P., Lukens W.W., Serne R.J., Qafoku N. et al. // J. Nucl. Mater. 2012. Vol. 429. N 1–3. P. 201–209. https://doi.org/10.1016/j.jnucmat.2012.06.004
- Singh B.K., Mahzan N.S., Abdul Rashid N.S., Isa S.A., Hafeez M.A., Saslow S., Um W. // Environ. Sci. Technol. 2023. Vol. 57. N 17. P. 6776–6798. https://doi.org/10.1021/acs.est.3c00129
- Arai Y., Powell B.A., Kaplan D.I. // J. Hazard. Mater. 2018. Vol. 342. P. 510–518. https://doi.org/10.1016/j.jhazmat.2017.08.049
- Luksic S.A., Riley B.J., Schweiger M., Hrma P. // J. Nucl. Mater. 2015. Vol. 466. P. 526–538. https://doi.org/10.1016/j.jnucmat.2015.08.052
- Skomurski F.N., Rosso K.M., Krupka K.M., McGrail B.P. // Environ. Sci. Technol. 2010. Vol. 44. P. 5855–5861. https://doi.org/10.1021/es100069x
- Smith F.N., Um W., Taylor C.D., Kim D.S., Schweiger M.J., Kruger A.A. // Environ. Sci. Technol. 2016. Vol. 50. N 10. P. 5216–5224. https://doi.org/10.1021/acs.est.6b00200
- McBeth J.M., Lloyd J.R., Law G.T.W., Livens F.R., Burke I.T., Morris K. // Mineral. Mag. 2011. Vol. 75. N 4. P. 2419–2430. https://doi.org/10.1180/minmag.2011.075.4.2419
- Pearce C.I., Icenhower J.P., Asmussen R.M., Tratnyek P.G., Rosso K.M., Lukens W.W., Qafoku N.P. // ACS Earth Space Chem. 2018. Vol. 2. N 6. P. 532–547. https://doi.org/10.1021/acsearthspacechem.8b00015
- El-Waer S., German K.E., Peretrukhin V.F. // J. Radioanal. Nucl. Chem. 1992. Vol. 157. P. 3–14. https://doi.org/10.1007/BF02039772
- Chen Z., Zhang P., Brown K.G., van der Sloot H.A., Meeussen J.C., Garrabrants A.C. et al. // J. Hazard. Mater. 2023. Vol. 449. Article 131004. https://doi.org/10.1016/j.jhazmat.2023.131004
- Pearce C.I., Moore R.C., Morad J.W., Asmussen R.M., Chatterjee S., Lawter A.R. et al. // Sci. Total Environ. 2020. Vol. 716. ID132849. https://doi.org/10.1016/j.scitotenv.2019.06.195
- German K.E., Shiryaev A.A., Safonov A.V., Obruchnikova Y.A., Ilin V.A., Tregubova V.E. // Radiochim. Acta. 2015. Vol. 103. N 3. P. 199. https://doi.org/10.1515/ract-2014–2369
- Fan D., Anitori R.P., Tebo B.M., Tratnyek P.G., Lezama Pacheco J.S., Kukkadapu R.K. et al. // Environ. Sci. Technol. 2014. Vol. 48. N 13. P. 7409–7417. https://doi.org/10.1021/es501607s
- Rodriguez D.M., Mayordomo N., Schild D., Azzam S.S.A., Brendler V., Mueller K., Stumpf T. // Chemosphere. 2021. Vol. 281. Article 130904. https://doi.org/10.1016/j.chemosphere.2021.130904
- Hatfield A.C. Aqueous geochemistry of rhenium and chromium in saltstone: Implications for understanding technetium mobility in saltstone: Doctoral Dissertation. Clemson Univ., 2013.
- Peretroukhine V., Sergeant C., Devès G., Poulain S., Vesvres M.H., Thomas B., Simonoff M. // Radiochim. Acta. 2006. Vol. 94. N 9–11. P. 665–669. https://doi.org/10.1524/ract.2006.94.9-11.665
- German K.E., Peretrukhin V.F., Belyaeva L.I., Kuzina O.V. // 4th Int. Conf. “Technetium and Rhenium in Chemistry and Nuclear Medicine,” Tc’94, Padua, Italy, Sept. 1994; J. Nucl. Biol. Med. 1994. Vol. 38. N 3. P. 406.
- German K.E., Peretrukhin V.F., Belyaeva L.I., Kuzina O.V. // Technetium and Rhenium Chemistry and Nuclear Medicine 4 / Eds. M. Nicolini, G. Bandoli, U. Mazzi. SGEditoriali, 1994. P. 93–97.
- Zhuang Η.E., Zheng J.S., Xia D.Y., Zhu Z.G. // Radiochim. Acta. 1995. Vol. 68. N 4. P. 245–250. https://doi.org/10.1524/ract.1995.68.4.245
- Данилов С.С., Фролова А.В., Тетерин А.Ю., Маслаков К.И., Тетерин Ю.А., Куликова С.А., Винокуров С.Е. // Радиохимия. 2021. Т. 63. № 6. С. 582. https://doi.org/10.31857/S0033831121060101
- Герасимов В.Н., Крючков С.В., Кузина А.Ф., Кулаков В.М., Пирожков С.В., Спицын В.И. // ДАН СССР. 1982. Т. 266. C. 148.
- Wester D.W., White D.H., Miller F.W., Dean R.T., Schreifels J.A., Hunt J.E. // Inorg. Chim. Acta. 1987. Vol. 131. N 2. P. 163. https://doi.org/10.1016/s0020-1693(00)96019-5
- Thompson M., Nunn A.D., Treher E.N. // Anal. Chem. 1986. Vol. 58. P. 3100. https://doi.org/10.1021/AC00127A041
- Shirley D.A. // Phys. Rev. B. 1972. Vol. 5. P. 4709. https://doi.org/10.1103/PhysRevB.5.4709
- Панов А.П. Пакет программ обработки спектров SPRO и язык программирования SL: Препринт ИАЭ-6019/15. М.: Ин-т атом. энергии, 1997. 31 c.
- Немошкаленко В.В., Алешин В.Г. Электронная спектроскопия кристаллов. Киев: Наук. думка, 1976. 336 с.
- Band I.M., Kharitonov Yu.I., Trzhaskovskaya M.B. // At. Data Nucl. Data Tables. 1979. Vol. 23. P. 443. https://doi.org/10.1016/0092-640X(79)90027-5.
- Gerasimov V.N., Kryutchkov S.V., German K.E., Kulakov V.M., Kuzina A.F. // Technetium and Rhenium in Chemistry and Nuclear Medicine. Vol. 3 / Eds. M. Nicolini, G. Bandoli, U. Mazzi. New York: Raven, 1990. P. 231–252.
- Нефедов В.И. Рентгеноэлектронная спектроскопия химических соединений: Справочник. М.: Химия, 1984. 256 с.
- Sosulnikov M.I., Teterin Yu.A. // J. Electron. Spectrosc. Relat. Phenom. 1992. Vol. 59. P. 111. https://doi.org/10.1016/0368-2048(92)85002-O
- Childs B.C., Braband H., Lawler K., Mast D.S., Bigler L., Stalder U. et al. // Inorg. Chem. 2016. Vol. 55. N 20. P. 10445. https://doi.org/10.1021/acs.inorgchem.6b01683
- Rodriguez E.E., Poineau F., Llobet A., Sattelberger A.P., Bhattacharjee J., Waghmare U.V. et al. // J. Am. Chem. Soc. 2007. Vol. 129. P. 10244. https://doi.org/10.1021/ja0727363
- Rodríguez D.M., Mayordomo N., Scheinost A.C., Schild D., Brendler V., Müller K., Stumpf T. // Environ. Sci. Technol. Vol. 2020. 54. P. 2678–2687. https://doi.org/10.1021/acs.est.9b05341
- Bagus P.S., Nelin C.J., Brundle C.R., Crist B.V., Lahiri N., Rosso K.M. // J. Chem. Phys. 2021. Vol. 154. Article 094709. https://doi.org/10.1063/5.0039765
- Zimmerman R., Steiner P., Claessen R., Reinert F., Hüfner S., Blaha P., Dufek P. // J. Phys. Condens. Matter. 1999. Vol. 11. P. 1657. https://doi.org/10.1088/0953-8984/11/7/002
- Miedema P.S., Borgatti F., Offi F., Panaccione G., Groota F.M.F. // J. Electron Spectrosc. Relat. Phenom. 2015. Vol. 203. P. 8. https://doi.org/10.1016/j.elspec.2015.05.003
- Biesinger M.C., Payne B.P., Grosvenor A.P., Laua L.W.M., Gerson A.R., Smart R. St.C. // Appl. Surf. Sci. 2011. Vol. 257. P. 2717. https://doi.org/10.1016/j.apsusc.2010.10.051
- Droubay T., Chambers S.A. // Phys. Rev. B. 2001. Vol. 64. Article 205414. https://doi.org/10.1103/PhysRevB.64.205414