Synthesis and Properties of Polyurea Greases Based on Silicone Fluids and Poly-α-olefin Oils

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Abstract

The paper describes an investigation of lubricants synthesized by thickening a dispersion medium consisting of silicone oil (PES-5) and poly-α-olefin oil (PAOM-12) with diureas of different compositions. The study revealed the effects of the compositions both of the dispersion medium and urea thickener, as well as their ratio in the lubricating formulation, on the major physicochemical properties of resultant greases. Increasing the content of the hydrocarbon component of the grease was shown to improve the physicochemical properties. Finally, the optimum grease composition was identified: introducing a polyurea thickener that contained diphenylmethane-4,4'-diisocyanate resulted in the synthesis of greases that had adequate operating characteristics and an improved wear performance.

About the authors

A. S. Lyadov

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: lyadov@ips.ac.ru
119991, Moscow, Russia

A. A. Kochubeev

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
119991, Moscow, Russia

O. P. Parenago

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Author for correspondence.
Email: petrochem@ips.ac.ru
119991, Moscow, Russia

References

  1. Синицын В.В. Пластичные смазки в СССР. Справочник. Издание 2-е, переработанное и дополненное. М.: Химия. 1984. 192 с.
  2. Rawat S.S., Harsha A.P. Current and future trends in grease lubrication // In: J. Katiyar, S. Bhattacharya, V. Patel, V. Kumar (eds) Automotive tribology. Energy, environment, and sustainability. Singapore: Springer. 2019. 342 р. https://doi.org/10.1007/978-981-15-0434-1_9
  3. Yu W., Xie H., Chen L., Zhu Z., Zhao J., Zhang Z. Graphene based silicone thermal greases // Physics Letters A. 2014. V. 378. № 3. P. 207-211. https://doi.org/10.1016/j.physleta.2013.10.017
  4. Chen H., Wei H., Chen M., Meng F., Li H., Li Q. Enhancing the effectiveness of silicone thermal grease by the addition of functionalized carbon nanotubes // Applied Surface Science. 2013. V. 283. P. 525-531. https://doi.org/10.1016/j.apsusc.2013.06.139
  5. Wang X., Jiang Q., Cui B., Wu K. Study on reliability and selection of silicone grease used for coating at the interface between cable and accessory // IEEE Transactions on Dielectrics and Electrical Insulation. 2022. https://doi.org/10.1109/TDEI.2022.3204528
  6. Jiang Z.Y., Li J.Y., Qu Z.G., Wang L., Miao J.Y. Theoretical analysis on thermal grease dry-out degradation in space environment // Intern. J. of Thermal Sciences. 2022. V. 179. N 107694. https://doi.org/10.1016/j.ijthermalsci.2022.107694
  7. Пиминова К.С., Левенто И.Ю., Стороженко П.А., Петров С.В. Универсальная пластичная смазка // Патент РФ № 2769692 (приоритет от 23.04.2021)
  8. Данилов А.М., Сентюрихина М.И., Емелина Г.А., Цыганова М.К., Молодкина В.В. Пластичная смазка для слаботочных электрических контактов // Патент РФ № 2535210 (приоритет от 17.10.2013)
  9. Павелко Г.Ф., Бордубанова Е.Г., Займовская Т.А., Бондаренко Г.Н., Лядов А.С., Паренаго О.П. Аномальная зависимость противоизносных свойств от состава смеси углеводородных масел с полиорганосилоксанами // Трение и износ. 2018. Т. 39. № 3. С. 299-304
  10. Pavelko G.F., Bordubanova E.G., Zaimovskaya T.A., Bondarenko G.N., Lyadov A.S., Parenago O.P. anomalous dependence of wear properties on mixture composition of hydrocarbon oils with polyorganosiloxanes // Friction and Wear. 2018. V. 39. № 3. P. 241-244. https://doi.org/10.3103/S1068366618030091
  11. Стороженко П.А., Демченко А.И., Левенто И.Ю., Нацюк С.Н., Хатуева Ж.С., Подойницин О.В., Левенто Л.К. Смазочное масло на основе жидких олигометилоктилсилоксанов и олигоэтилоктилсилоксанов // Патент РФ № 2673482 (приоритет от 16.02.2018).
  12. Лядов А.С., Максимова Ю.М., Алексеева О.А., Ильин С.О., Паренаго О.П., Антонов С.В. Особенности пластичных смазок на основе полиальфаолефиновых масел с уреатными загустителями различного строения // Журн. прикладной химии. 2018. Т. 91. № 11. С. 1523-1530. https://doi.org/10.1134/S0044461818110014
  13. Lyadov A.S., Maksimova Yu.M., Ilyin S.O., Gorbacheva S.N., Parenago O.P., Antonov S.V. Specific Features of Plastic Lubricants Based on Poly-α-olefin Oils with Ureate Thickeners of Various Structures" // Russ. J. Appl. Chemistry. 2018. V. 91. № 11. P. 1733-1739. https://doi.org/10.1134/S1070427218011014.

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