FILLING OF CHANNELS OF THE ZEOLITE FRAMEWORK IN TRIGONAL POLAR NONABORATE Ва 3 Na 0.9 (OH) 1.9 [B 9 O 16 ][B(OH) 3 ]

A. P. Topnikova; Топникова А. П.; E. L. Belokoneva; Белоконева Е. Л.; O. V. Dimitrova; Димитрова О. В.; A. S. Volkov; Волков А. С.; L. V. Zorina; Зорина Л. В.

doi:10.31857/S0023476123020200

FILLING OF CHANNELS OF THE ZEOLITE FRAMEWORK IN TRIGONAL POLAR NONABORATE Ва₃Na_0.9(OH)_1.9[B₉O₁₆][B(OH)₃]

Authors: Topnikova A.P.¹, Belokoneva E.L.¹, Dimitrova O.V.¹, Volkov A.S.¹, Zorina L.V.²
Affiliations:
1. Lomonosov Moscow State University, Moscow, 119991 Russia
2. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432 Russia
Issue: Vol 68, No 2 (2023)
Pages: 223-227
Section: СТРУКТУРА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0023-4761/article/view/137365
DOI: https://doi.org/10.31857/S0023476123020200
EDN: https://elibrary.ru/BSWCKC
ID: 137365

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Abstract
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Abstract

Crystals of the new trigonal borate Ва₃Na_0.9(OH)_1.9[B₉O₁₆][B(OH)₃] (sp. gr. P31c, a =10.23684(15) Å, c = 8.72926(13) Å) were prepared by the mild hydrothermal synthesis. The filling of the channels in the framework of the polar nonaborate was found to differ from that determined previously. It is consistent with the main features of this structure type with the preservation of sassoline molecules in the channels. The structure contains an additional ОН group, which is involved in the coordination of Ва.

Keywords

HYDROTHERMAL SYNTHESIS, TRIGONAL POLAR NONABORATE

References

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