电邮这篇文章 High-Spin Photolysis Products of 1,3,5-Triazido-2,4,6-trichlorobenzene in a Frozen 2-Methyltetrahydrofuran Solution
- 作者: Chapyshev S.1, Korchagin D.1
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隶属关系:
- Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
- 期: 卷 57, 编号 4 (2023)
- 页面: 276-281
- 栏目: ФОТОХИМИЯ
- URL: https://journals.rcsi.science/0023-1193/article/view/139991
- DOI: https://doi.org/10.31857/S002311932304006X
- EDN: https://elibrary.ru/QNEWZZ
- ID: 139991
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详细
High-spin products of photolysis of 1,3,5-triazido-2,4,6-trichlorobenzene in a 2-methyltetrahydrofuran solution frozen at 6 K has been studied using EPR spectroscopy in combination with quantumchemical calculations. It has been found that the photolysis of this triazide leads to the formation of a mixture of triplet 1,3-diazido-2,4,6-trichlorophenyl-5-nitrene, quintet 1-azido-2,4,6-trichlorophenyl-3,5-dinitrene, and septet 2,4,6-trichlorophenyl-1,3,5-trinitrene. The solvent effect on the EPR spectra and the magnetic
characteristics of nitrenes has been studied.
作者简介
S. Chapyshev
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: chap@icp.ac.ru
Chernogolovka, Moscow oblast, 142432 Russa
D. Korchagin
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: chap@icp.ac.ru
Chernogolovka, Moscow oblast, 142432 Russa
参考
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