Мақаланы E-mail арқылы жіберу High-Spin Photolysis Products of 1,3,5-Triazido-2,4,6-trichlorobenzene in a Frozen 2-Methyltetrahydrofuran Solution
- Авторлар: Chapyshev S.1, Korchagin D.1
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Мекемелер:
- Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
- Шығарылым: Том 57, № 4 (2023)
- Беттер: 276-281
- Бөлім: ФОТОХИМИЯ
- URL: https://journals.rcsi.science/0023-1193/article/view/139991
- DOI: https://doi.org/10.31857/S002311932304006X
- EDN: https://elibrary.ru/QNEWZZ
- ID: 139991
Дәйексөз келтіру
Ашық рұқсат
Рұқсат берілді
Тек жазылушылар үшін
Аннотация
High-spin products of photolysis of 1,3,5-triazido-2,4,6-trichlorobenzene in a 2-methyltetrahydrofuran solution frozen at 6 K has been studied using EPR spectroscopy in combination with quantumchemical calculations. It has been found that the photolysis of this triazide leads to the formation of a mixture of triplet 1,3-diazido-2,4,6-trichlorophenyl-5-nitrene, quintet 1-azido-2,4,6-trichlorophenyl-3,5-dinitrene, and septet 2,4,6-trichlorophenyl-1,3,5-trinitrene. The solvent effect on the EPR spectra and the magnetic
characteristics of nitrenes has been studied.
Негізгі сөздер
Авторлар туралы
S. Chapyshev
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: chap@icp.ac.ru
Chernogolovka, Moscow oblast, 142432 Russa
D. Korchagin
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: chap@icp.ac.ru
Chernogolovka, Moscow oblast, 142432 Russa
Әдебиет тізімі
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