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Barrier discharge conversion of gaseous olefins
- Authors: Ryabov A.Y.1, Kudryashov S.V.1
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Affiliations:
- Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
- Issue: Vol 58, No 6 (2024)
- Pages: 483-488
- Section: PLASMA CHEMISTRY
- URL: https://journals.rcsi.science/0023-1193/article/view/281555
- DOI: https://doi.org/10.31857/S0023119324060081
- EDN: https://elibrary.ru/THKSNK
- ID: 281555
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Abstract
The oxidation of olefins С2–С4 in a barrier discharge in the presence of water has been investigated, with the formation of oxygen-containing compounds and various hydrocarbons С1–С5+ of limited and unsaturated structure being observed. The initial olefin’s molecular weight and structure have been found to exert a significant influence on the direction of the reaction. In the ethylene-propylene-butylene series, the proportion of oxygen-containing compounds increases from 28.1, 74.3 and 66.7 wt%, respectively. The oxidation of isobutene isomasalic aldehyde and acetone, with a content of 53 and 21 wt. %, respectively, primarily yields the formation of these compounds. In the case of the oxidation of butene-1 and butene-2, the predominant products are butanol-2, with a yield of up to 26 wt. %.
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About the authors
A. Y. Ryabov
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: a.y.ryabov@yandex.ru
Russian Federation, Tomsk
S. V. Kudryashov
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Email: a.y.ryabov@yandex.ru
Russian Federation, Tomsk
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