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Plasma-chemical modification of polyethylene surface for copolymerization with diallyldimethylammonium chloride
- Authors: Smirnov S.A.1, Shikova T.G.1, Kholodkov I.V.1, Maltsev A.A.2, Misin V.M.2
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- N.M. Emanuel Institute of Biochemical Physics RAS
- Issue: Vol 58, No 4 (2024)
- Pages: 329-334
- Section: PLASMA CHEMISTRY
- URL: https://journals.rcsi.science/0023-1193/article/view/274668
- DOI: https://doi.org/10.31857/S0023119324040135
- EDN: https://elibrary.ru/TPFSEB
- ID: 274668
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Abstract
Changes in the composition of the surface layer of polyethylene film after treatment in the positive column of glow discharge of direct current in the flow of oxygen and argon have been studied. The possibility of copolymerization of diallyldimethylammonium chloride monomer and polyethylene surface modified in plasma is shown.
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About the authors
S. A. Smirnov
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: sas@isuct.ru
Russian Federation, Ivanovo
T. G. Shikova
Ivanovo State University of Chemistry and Technology
Email: sas@isuct.ru
Russian Federation, Ivanovo
I. V. Kholodkov
Ivanovo State University of Chemistry and Technology
Email: sas@isuct.ru
Russian Federation, Ivanovo
A. A. Maltsev
N.M. Emanuel Institute of Biochemical Physics RAS
Email: sas@isuct.ru
Russian Federation, Ivanovo
V. M. Misin
N.M. Emanuel Institute of Biochemical Physics RAS
Email: sas@isuct.ru
Russian Federation, Ivanovo
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Supplementary files
Supplementary Files
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1.
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2.
Fig. 1. IR spectrum of PE films: (a) after plasma treatment; 1 – original sample; 2 – sample treated in oxygen plasma; 3 – sample treated in argon plasma. Plasma treatment conditions: pressure 100 Pa, discharge current 80 mA, treatment time 300 s. (b) after mDDA grafting; 1 – sample treated in argon plasma at a discharge current of 80 mA, after holding in mDDA solution for 1 h; 2 – this sample after holding in distilled water (1 h); 3 – this sample after “active” rinsing in water.
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3.
Fig. 2. AFM images of polyethylene films: (a) original sample; (b) treated in oxygen plasma; (c) treated in argon plasma. Discharge current 80 mA, gas pressure 100 Pa.
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4.
Fig. 3. Photograph of water droplets and mDDA solution on the surface of PE film: (a) water droplet on the original sample; (b) water droplet on the sample treated in oxygen plasma at a current of 50 mA; (c) monomer solution droplet on the sample treated in oxygen plasma at a current of 50 mA; (d) water droplet on the sample treated in oxygen plasma after grafting and active washing of the monomer.
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5.
Fig. 4. AFM images of PE film in phase contrast: (a) after treatment in argon plasma at a discharge current of 80 mA and a pressure of 100 Pa; (b) after treatment in argon plasma, grafting and active washing of the monomer.
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