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Methacrylate-Containing n-Derivatives of N,N-Diethyl-4-(Phenyldiazenyl)Aniline as Initiators in Two-Photon Polymerization
- Authors: Arsenyev M.V.1, Zhiganshin E.R.1, Kolymagin D.A.2, Ilyichev V.A.1, Kovylin R.S.1, Vitukhnovsky A.G.2,3, Chesnokov S.A.1
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Affiliations:
- G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
- Moscow Institute of Physics and Technology (National Research University)
- P.N. Lebedev Physical Institute of the Russian Academy of Sciences
- Issue: Vol 58, No 3 (2024)
- Pages: 190-197
- Section: ФОТОХИМИЯ
- URL: https://journals.rcsi.science/0023-1193/article/view/267362
- DOI: https://doi.org/10.31857/S0023119324030022
- EDN: https://elibrary.ru/UUYGVO
- ID: 267362
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Abstract
The possibility of using a number of methacrylate-containing N,N-diethyl-4-(phenyldiazenyl)anilines with various para-substituents with respect to the azo group (-H, -Br, -NO2) as photoinitiators of radical polymerization is considered. The electrochemical and photoluminescent properties of these compounds have been studied. In the presence of azo dyes, two-photon photopolymerization of pentaerythritol triacrylate was carried out by focused radiation from a femtosecond laser with a wavelength of 780 nm. Structures with minimum linear element sizes of 94 ± 5 nm were obtained by DLW nanolithography, as well as 3D microstructures of complex architecture.
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About the authors
M. V. Arsenyev
G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: zhiganshinae@mail.ru
Russian Federation, Nizhny Novgorod
E. R. Zhiganshin
G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Author for correspondence.
Email: zhiganshinae@mail.ru
Russian Federation, Nizhny Novgorod
D. A. Kolymagin
Moscow Institute of Physics and Technology (National Research University)
Email: zhiganshinae@mail.ru
Russian Federation, Dolgoprudny
V. A. Ilyichev
G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: zhiganshinae@mail.ru
Russian Federation, Nizhny Novgorod
R. S. Kovylin
G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: zhiganshinae@mail.ru
Russian Federation, Nizhny Novgorod
A. G. Vitukhnovsky
Moscow Institute of Physics and Technology (National Research University); P.N. Lebedev Physical Institute of the Russian Academy of Sciences
Email: zhiganshinae@mail.ru
Russian Federation, Dolgoprudny; Moscow
S. A. Chesnokov
G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: zhiganshinae@mail.ru
Russian Federation, Nizhny Novgorod
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