Radiolytic Inactivation of Ponceau 4R Mutagenicity in Aqueous Solution

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The electron-beam treatment of an aqueous solution of the azo dye Ponceau 4R (0.02 g/dm3) at a dose of 1.5 kGy in air led to the complete elimination of color and genotoxicity. The addition of OH radicals to the system of conjugated bonds of the dye (the formation of OH adducts) was a key radiolytic process, which led to the elimination of side groups with lower binding energies

作者简介

A. Ponomarev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: ponomarev@ipc.rssi.ru
Moscow, 119071 Russia

E. Kholodkova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: ponomarev@ipc.rssi.ru
Moscow, 119071 Russia

I. Zotova

St. Petersburg State University; Vavilov Institute of General Genetics, St. Petersburg Branch, Russian Academy of Sciences

Email: ponomarev@ipc.rssi.ru
St. Petersburg, 199034 Russia; St. Petersburg, 199034 Russia

A. Shumega

St. Petersburg State University

Email: ponomarev@ipc.rssi.ru
St. Petersburg, 199034 Russia

E. Stepchenkova

St. Petersburg State University; Vavilov Institute of General Genetics, St. Petersburg Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: ponomarev@ipc.rssi.ru
St. Petersburg, 199034 Russia; St. Petersburg, 199034 Russia

参考

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  6. Kholodkova E.M., Ponomarev A.V. // High Energy Chem. 2023. V. 57. P. 146. https://doi.org/10.1134/S0018143923020078
  7. Ponomarev A.V., Ershov B.G. // Environ. Sci. Technol. 2020. V. 54. P. 5331. https://doi.org/10.1021/acs.est.0c00545
  8. Traven V.F. // Frontier Orbitals and Properties of Organic Molecules (Ellis Horwood Series in Organic Chemistry), Mellor J. ed. Ellis Horwood Ltd, New York. 1992.
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  10. Kim Yuri, Ershov B.G., Ponomarev A.V. // High Energy Chem. 2020, V. 54(6). P. 462. https://doi.org/10.1134/S0018143920060089

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版权所有 © А.В. Пономарев, Е.М. Холодкова, И.В. Зотова, А.Р. Шумега, Е.И. Степченкова, 2023

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