Oxidative and Nonoxidative Conversion of Ethylene in Dielectric Barrier Discharge

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Abstract

The oxidative and nonoxidative conversion of ethylene in a dielectric barrier discharge in the presence of water with the formation of predominantly unsaturated compounds (acetylene, butene, butadiene) has been studied. The efficiency of ethylene conversion in argon is shown in comparison with its oxidation by air into oxygenates. A simple theoretical estimate of the energy loss of discharge electrons in the feed gas mixture and simple kinetic calculations make it possible to explain both the change in the degree of ethylene conversion and the direction of the process

About the authors

A. Yu. Ryabov

Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences

Email: a.y.ryabov@yandex.ru
Tomsk, 634055 Russia

S. V. Kudryashov

Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: a.y.ryabov@yandex.ru
Tomsk, 634055 Russia

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