电邮这篇文章 Crystal structure of Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O
- 作者: Abramov P.A.1,2, Sokolov M.N.1,2
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隶属关系:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- 期: 卷 58, 编号 7 (2017)
- 页面: 1411-1417
- 栏目: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161641
- DOI: https://doi.org/10.1134/S0022476617070198
- ID: 161641
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详细
The diffusion of acetone vapor into a Na7H[Nb6O19] solution at pH 9.5 results in the crystallization of the Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O (1) complex characterized by X-ray diffraction. The sodium cation coordination to a triangular face of the anion enables the determination of anion protonation sites by blocking the disordering and the formation of strong hydrogen bonds between the anions.
作者简介
P. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
编辑信件的主要联系方式.
Email: abramov@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk
M. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: abramov@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk
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