Email this article Crystal structure of Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O
- Authors: Abramov P.A.1,2, Sokolov M.N.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Issue: Vol 58, No 7 (2017)
- Pages: 1411-1417
- Section: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161641
- DOI: https://doi.org/10.1134/S0022476617070198
- ID: 161641
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Abstract
The diffusion of acetone vapor into a Na7H[Nb6O19] solution at pH 9.5 results in the crystallization of the Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O (1) complex characterized by X-ray diffraction. The sodium cation coordination to a triangular face of the anion enables the determination of anion protonation sites by blocking the disordering and the formation of strong hydrogen bonds between the anions.
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About the authors
P. A. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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