Отправить статью по E-mail Crystal Structure and Catalytic Property of an Oxidomolybdenum(VI) Complex Derived from N′-(2-Hydroxy-3,5-Di-Tert-Butylbenzylidene)-4-Methylbenzohydrazide
- Авторы: Peng D.1,2
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Учреждения:
- Key Laboratory of Surface and Interface Science of Henan Province, School of Material and Chemical Engineering
- Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration
- Выпуск: Том 59, № 3 (2018)
- Страницы: 589-594
- Раздел: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161913
- DOI: https://doi.org/10.1134/S0022476618030125
- ID: 161913
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Аннотация
With a tridentate Schiff base ligand N′-(2-hydroxy-3,5-di-tert-butylbenzylidene)-4-methylbenzohydrazide (H2L) and MoO2(acac)2, an oxidomolybdenum(VI) complex is prepared and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. The complex crystallizes in the monoclinic space group C2/c with unit cell dimensions a = 20.187(2) Å, b = 7.9094(8) Å, c = 33.233(3) Å, β = 97.394(2)°, V = 5262.1(9) Å3, Z = 8, R1 = 0.0491, and wR2 = 0.1322. The single crystal X-ray diffraction analysis reveals that the Mo atom is coordinated by NOO donor atoms of the Schiff base ligand, the methanol O atom, and two oxo groups in an octahedral coordination. Catalytic oxidation of the complex on some olefins is performed.
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Об авторах
D.-L. Peng
Key Laboratory of Surface and Interface Science of Henan Province, School of Material and Chemical Engineering; Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration
Автор, ответственный за переписку.
Email: pengdonglai2015@sina.com
Китай, Zhengzhou; Zhengzhou
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