Email this article Crystal Structure and Catalytic Property of an Oxidomolybdenum(VI) Complex Derived from N′-(2-Hydroxy-3,5-Di-Tert-Butylbenzylidene)-4-Methylbenzohydrazide
- Authors: Peng D.1,2
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Affiliations:
- Key Laboratory of Surface and Interface Science of Henan Province, School of Material and Chemical Engineering
- Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration
- Issue: Vol 59, No 3 (2018)
- Pages: 589-594
- Section: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161913
- DOI: https://doi.org/10.1134/S0022476618030125
- ID: 161913
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Abstract
With a tridentate Schiff base ligand N′-(2-hydroxy-3,5-di-tert-butylbenzylidene)-4-methylbenzohydrazide (H2L) and MoO2(acac)2, an oxidomolybdenum(VI) complex is prepared and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. The complex crystallizes in the monoclinic space group C2/c with unit cell dimensions a = 20.187(2) Å, b = 7.9094(8) Å, c = 33.233(3) Å, β = 97.394(2)°, V = 5262.1(9) Å3, Z = 8, R1 = 0.0491, and wR2 = 0.1322. The single crystal X-ray diffraction analysis reveals that the Mo atom is coordinated by NOO donor atoms of the Schiff base ligand, the methanol O atom, and two oxo groups in an octahedral coordination. Catalytic oxidation of the complex on some olefins is performed.
About the authors
D.-L. Peng
Key Laboratory of Surface and Interface Science of Henan Province, School of Material and Chemical Engineering; Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration
Author for correspondence.
Email: pengdonglai2015@sina.com
China, Zhengzhou; Zhengzhou
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