Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)3
- Autores: Anyushin A.V.1, Kompan’kov N.B.1, Abramov P.A.1, Sokolov M.N.1,2,3
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Afiliações:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Kazan Federal University
- Edição: Volume 60, Nº 7 (2019)
- Páginas: 1072-1079
- Seção: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/162146
- DOI: https://doi.org/10.1134/S0022476619070072
- ID: 162146
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Resumo
A reaction of RhCl3·3H2O with P(CH2OH)3 (THP) and H2S in methanol results in the formation of a new trinuclear complex [Rh3(μ3-S)2(μ2-S)(μ2-Cl)2(THP)6]Cl (1) with a yield of 29%. The structure of 1 is determined by X-ray crystallography. With the same initial compounds with hexamethyldisilthiane as a sulfide source a binuclear [Rh2(μ2-S2)(μ2-S)(THP)6]2+ complex is obtained in which mono- and disulfide bridges are present simultaneously. The latter is isolated and structurally characterized as [Rh2(μ-S2)(μ2-S)(THP)6][Mo6Cl14]·0.6MeOH (2) with a yield of 12%. The compounds obtained are characterized by mass spectrometry and 31P NMR spectra.
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Sobre autores
A. Anyushin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: caesar@niic.nsc.ru
Rússia, Novosibirsk
N. Kompan’kov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: caesar@niic.nsc.ru
Rússia, Novosibirsk
P. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: caesar@niic.nsc.ru
Rússia, Novosibirsk
M. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University; Kazan Federal University
Autor responsável pela correspondência
Email: caesar@niic.nsc.ru
Rússia, Novosibirsk; Novosibirsk; Kazan
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