New One-Dimensional Chain Polymer Based on [Zn2(OCO)2] Rhomboid Clusters


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Abstract

A one-dimensional Zn(II) complex [Zn(NO2-BDC)(NPT)2]n (1) (NO2-H2BDC = 5-nitro-1,3-benzenedicarboxylic acid, NPT = 1-(4-nitrophenyl)-1,2,4-triazole) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is an infinite ladder-like one-dimensional chain based on [Zn2(OCO)2] rhomboid clusters. The thermal stability and luminescence properties of complex 1 are investigated.

About the authors

J. Qian

School of Chemistry and Environmental Engineering

Email: wjyctu@hotmail.com
China, Yancheng, Jiangsu

J. Wang

School of Chemistry and Environmental Engineering

Author for correspondence.
Email: wjyctu@hotmail.com
China, Yancheng, Jiangsu

N.-N. Chen

School of Chemistry and Environmental Engineering

Email: wjyctu@hotmail.com
China, Yancheng, Jiangsu

J.-Q. Tao

School of Chemistry and Environmental Engineering

Email: wjyctu@hotmail.com
China, Yancheng, Jiangsu

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